Search Results

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

The emissions reduction potential of neat GTL (Gas to Liquids: Fischer-Tropsch synthetic gas-oil derived from natural gas) fuels has been preliminarily evaluated by three different latest-generation diesel engines with different displacements. In addition, differences in combustion phenomena between the GTL fuels and baseline diesel fuel have been observed by means of a single cylinder engine with optical access. From these findings, one of the engines has been modified to improve both exhaust emissions and fuel consumption simultaneously, assuming the use of neat GTL fuels. The conversion efficiency of the NOx (oxides of nitrogen) reduction catalyst has also been improved.

A computational and experimental study has been carried out to assess the high load efficiency and emissions potential of a combustion system designed to operate on low octane gasoline (or naphtha). The “naphtha engine” concept utilizes spark ignition at low load, HCCI at intermediate load, and compression ignition at high load; this paper focuses on high load (compression ignition) operation. Experiments were carried out in a single cylinder diesel engine with compression ratio of 16 and a common rail injector/fuel delivery system. Three fuels were examined: a light naphtha (RON∼59, CN∼34), heavy naphtha (RON∼66, CN∼31), and heavy naphtha additized with cetane improver (CN∼40). With single fuel injection near top dead center (TDC) (diesel-like combustion), excessive combustion noise is generated as the load increases. This noise limits the maximum power, in agreement with the CFD predictions. The noise-limited maximum power increases somewhat with the use of single pilot injection.

To meet future stringent emission regulations such as Euro6, the design and control of diesel exhaust after-treatment systems will become more complex in order to ensure their optimum operation over time. Moreover, because of the strong pressure for CO₂ emissions reduction, the average exhaust temperature is expected to decrease, posing significant challenges on exhaust after-treatment. Diesel Oxidation Catalysts (DOCs) are already widely used to reduce CO and hydrocarbons (HC) from diesel engine emissions. In addition, DOC is also used to control the NO₂/NOx ratio and to generate the exothermic reactions necessary for the thermal regeneration of Diesel Particulate Filter (DPF) and NOx Storage and Reduction catalysts (NSR). The expected temperature decrease of diesel exhaust will adversely affect the CO and unburned hydrocarbons (UHC) conversion efficiency of the catalysts. Therefore, the development cost for the design and control of new DOCs is increasing.

A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.

Alcohol fuels that can be produced from cellulose continue to become more widely used in gasoline engines. This research investigated the application of alcohol to diesel engines with the aims of improving the combustion of diesel engines and of utilizing alternative fuels. Two methods were compared, a method in which alcohol is injected into the air intake system and a method in which alcohol is blended in advance into the diesel fuel. Alcohol is an oxygenated fuel and so the amount of soot that is emitted is small. Furthermore, blended fuels have characteristics that help promote mixture formation, which can be expected to reduce the amount of soot even more, such as a low cetane number, low viscosity, low surface tension, and a low boiling point. Ethanol has a strong moisture-absorption attribute and separates easily when mixed with diesel fuel. Therefore, 1-butanol was used since it possesses a strong hydrophobic attribute and does not separate easily.

This paper presents a modeling method for prediction of low-frequency road noise in a steady-state condition where rotating tires are excited by actual road profile undulation input. The proposed finite element (FE) tire model contains not only additional geometric stiffness related to inflation pressure and axle load but also Coriolis force and centrifugal force effects caused by tire rotation for precise road noise simulation. Road inputs act on the nodes of each rib in the contact patch of the stationary tire model and move along them at the driving velocity. The nodes are enforced to displace in frequency domain based on the measured road profile. Tire model accuracy was confirmed by the spindle forces on the rotating chassis drum up to 100Hz where Coriolis force effect should be considered. Full vehicle simulation results showed good agreement with the vibration measurement of front/rear suspension at two driving velocities.

In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.

This paper proposes a novel method of verifying comprehensive driver model used for the evaluation of driving safety systems, which is achieved by coupling the traffic simulation and the driving simulator (DS). The method consists of three-step procedure. In the first step, an actual driver operates a DS vehicle in the traffic flow controlled by the traffic simulation. Then in the next step, the actual driver is replaced by a driver model and the surrounding vehicle maneuvers are replayed using the recorded data from the first step. Then, the maneuver by the driver model is compared directly with the actual driver's maneuver along the simulation time steps.

A novel plant modeling method called High Level Modeling (HLM) to design and develop control-oriented plant model is introduced. The HLM method is specifically designed to expose the design intention at physics level of a target physical system in a straightforward manner so that plant models can be efficiently understood and peer-reviewed from the physical standpoint. The method also enables construction of system equations from the design information based on simple formal rules which guarantees conservation laws. To show the effectiveness of the HLM approach through a concrete use case, it is applied to turbocharger radial compressor modeling, and analysis on the model equations is performed by deriving compressor speed lines and efficiency.

This paper considers an application of reference governor (RG) to automotive diesel aftertreatment temperature control. Recently, regulations on vehicle emissions have become more stringent, and engine hardware and software are expected to be more complicated. It is getting more difficult to guarantee constraints in control systems as well as good control performance. Among model-based control methods that can directly treat constraints, this paper focuses on the RG, which has recently attracted a lot of attention as one method of model prediction-based control. In the RG, references in tracking control are modified based on future prediction so that the predicted outputs in a closed-loop system satisfy the constraints. This paper proposes an online RG algorithm, taking account of the real-time implementation on engine embedded controllers.

The reduction of the heat loss from the in-cylinder gas to the combustion chamber wall is one of the key technologies for improving the thermal efficiency of internal combustion engines. This paper describes an experimental verification of the “temperature swing” insulation concept, whereby the surface temperature of the combustion chamber wall follows that of the transient gas. First, we focus on the development of “temperature swing” insulation materials and structures with the thermo-physical properties of low thermal conductivity and low volumetric heat capacity. Heat flux measurements for the developed insulation coating show that a new insulation material formed from silica-reinforced porous anodized aluminum (SiRPA) offers both heat-rejecting properties and reliability in an internal combustion engine. Furthermore, a laser-induced phosphorescence technique was used to verify the temporal changes in the surface temperature of the developed insulation coating.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

Compatibility is important in order to secure mutual protection in collisions between large and small vehicles. To enhance compatibility, good structural interaction and stiffness matching are important elements. This paper proposes a test method that uses a moving deformable barrier (MDB) to evaluate compatibility performance that includes not only structural interaction but also stiffness matching. This new deformable barrier is aimed at the simulation of offset Vehicle-to-Vehicle collisions with compact vehicles. This simulation is based on real world crash research, and takes into account three separate load interactions between the impacting vehicles. These areas of interaction include the impacting vehicle's power unit to the opposing vehicle's wheel, the impacting vehicle's lower rail to the opposing vehicle's lower rail, and the impacting vehicle's wheel to the opposing vehicle's power unit.

This paper describes the development of a simplified fracture finite element (FE) model for resistance spot welds (RSW) of ultra-high-strength steel (UHSS) that can be incorporated into large-scale vehicle FE model. It is known that the RSW of UHSS generates two types of fracture modes: heat-affected zone (HAZ) and nugget zone fractures. Lap shear and peeling coupon tests using UHSS sheets found that the different RSW fracture modes occurred at different nugget diameters. To analyze this phenomenon, detailed simulated coupon tests were carried out using solid hexahedral elements. The analytical results revealed that RSW fractures are defined by both the application of plastic strain on the elements and the stress triaxiality state of the elements. A detailed model incorporating a new fracture criteria model recreated the different UHSS RSW fracture modes and achieved a close correlation with the coupon test results.

Abnormal combustion referred to as Low Speed Pre-Ignition (LSPI) may restrict low speed torque improvements in turbocharged Direct Injection (DI) - Spark Ignition (SI) Engines. Recent investigations have reported that the auto-ignition of an engine oil droplet from the piston crevice in the combustion chamber may cause unexpected and random LSPI. This study shows that engine oil formulations have significant effects on LSPI. We found that the spontaneous ignition temperature of engine oil, as determined using High-Pressure Differential Scanning Calorimetry (HP-DSC) correlates with LSPI frequency in a prototype turbocharged DI-SI engine. Based on these findings, we believe that the oxidation reaction of the oil is very important factor to the LSPI. Our test data, using a prototype engine, shows both preventative and contributory effects of base oil and metal-based engine oil additives.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

The purpose of this study is to analyze the piston skirt friction reduction effect of a diamond-like carbon (DLC)-coated wrist pin. The floating liner method and elasto-hydrodynamic lubrication (EHL) simulation were used to analyze piston skirt friction. The experimental results showed that a DLC-coated wrist pin reduced cylinder liner friction, and that this reduction was particularly large at low engine speeds and large pin offset conditions. Friction was particularly reduced at around the top and bottom dead center positions (TDC and BDC). EHL simulation confirmed that a DLC-coated wrist pin affects the piston motion and reduces the contact pressure between the piston skirt and cylinder liner.

This article proposes a rubber suspension bushing model considering amplitude dependence as a useful tool at the initial design phase. The purpose of this study is not to express physical phenomena accurately and in detail and to explore the truth academically, but to provide a useful design method for initial design phase. Experiments were carried out to verify several dynamic characteristics of rubber bushings under vibration up to a frequency of 100 Hz, which is an important frequency range when designing ride comfort performance. When dynamic characteristic theory and the geometrical properties of the force-displacement characteristic curve were considered using these dynamic characteristics as assumptions, an equation was derived that is capable of calculating the dynamic stiffness under an arbitrary amplitude by identifying only two general design parameters (dynamic stiffness and loss factor) under a reference amplitude.

It is difficult to improve tire cavity noise since the pressure of cavity resonance acts as a compelling force, and its low damping and high gain characteristics dominate the vibration of both the suspension and body. For this reason, the analysis described in this article aimed to clarify the design factors involved and to improve this phenomenon at the source. This was accomplished by investigating the acoustic coupling vibration mode of the wheel, which is the component that transmits the pressure of cavity resonance at first. In addition, the vibration characteristic of suspension was investigated also. A speaker-equipped sound pressure generator inside the tire and wheel assembly was developed and used to infer that wheel vibration under cavity resonance is a forced vibration mode with respect to the cavity resonance pressure distribution, not an eigenvalue mode, and this phenomenon may therefore be improved by optimizing the out-of-plane torsional stiffness of the disk.